Issue 18, 1995

Nickel-catalysed substitution reactions of allylic compounds with soft nucleophiles: an efficient alternative to palladium catalysis

Abstract

Substitution reactions of allyl alcohol derivatives 1ac with diethylamine, phenol and dimethyl malonate are efficiently carried out in the presence of Ni(dppb)2(dppb = 1,2-diphenylphosphinobutane) as catalyst and ammonium salts or bases as promoters or co-reagents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1863-1864

Nickel-catalysed substitution reactions of allylic compounds with soft nucleophiles: an efficient alternative to palladium catalysis

H. Bricout, J. Carpentier and A. Mortreux, J. Chem. Soc., Chem. Commun., 1995, 1863 DOI: 10.1039/C39950001863

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