Issue 9, 1995

Synthesis of shidasterone and the unambiguous determination of its configuration at C-22

Abstract

Shidasterone 1 is prepared from 2,3-isopropylidene-22-mesylate 20-hydroxyecdysone 4 by three different synthetic sequences; mechanistic considerations together with independent NOE studies reveal a (22R) configuration for Shidasterone 1.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 933-934

Synthesis of shidasterone and the unambiguous determination of its configuration at C-22

P. G. Roussel, N. J. Turner and L. N. Dinan, J. Chem. Soc., Chem. Commun., 1995, 933 DOI: 10.1039/C39950000933

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