The first example is reported of a palladium-catalysed Cyclodimerization of butadiene to 2-vinylmethylenecyclopentane occurring in catalytic turnovers and yields far superior to the nickel-based systems, which are claimed to be specific for cyclodimerization reactions.
F. Bergamini, F. Panella, R. Santi and E. Antonelli, J. Chem. Soc., Chem. Commun., 1995, 931 DOI: 10.1039/C39950000931
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