Following administration of both enantiomers of the pentaketide intermediate in the biosynthesis of aspyrone labelled with deuterium to Aspergillus melieus, it is shown by 2H NMR that only the (S)-isomer is incorporated intact into the natural product.
A. M. Hill and J. Staunton, J. Chem. Soc., Chem. Commun., 1995, 861 DOI: 10.1039/C39950000861
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