A three-component complex consisting of a coordinating ring, a copper(I) centre and a difunctionalized fragment threaded inside the ring is reacted with a C60 derivative to afford a soluble rotaxane with two fullerenes as stoppers in 15% yield.
F. Diederich, C. Dietrich-Buchecker, J. Nierengarten and J. Sauvage, J. Chem. Soc., Chem. Commun., 1995, 781 DOI: 10.1039/C39950000781
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