SCHEDULED MAINTENANCE
A range of α,α-dideuteriated phosphonic esters has been prepared by deuteriolysis of α-silylated α-phosphonylated carbanions with D2O as deuterium source. In most cases, incorporation of deuterium is greater than 95% and the yields are good to excellent. The title products are potential tracer compounds in many biological and industrial applications.
S. Berté-Verrando, F. Nief, C. Patois and P. Savignac, J. Chem. Soc., Perkin Trans. 1, 1994, 821 DOI: 10.1039/P19940000821
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