Lineshape changes in the solid-state 13C NMR spectrum of [Cr(η6-C6H6)(CO)3] over the temperature range 203–393 K have been shown to be consistent with reorientation of the Cr(CO)3 unit (with free energy of activation estimated to be 70 ± 5 kJ mol–1), and in-plane reorientation of the benzene molecule.
A. E. Aliev, K. D. M. Harris, F. Guillaume and P. J. Barrie, J. Chem. Soc., Dalton Trans., 1994, 3193 DOI: 10.1039/DT9940003193
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