Issue 21, 1994

Preparation of 1,1′-bis[(diphenylphosphino)methyl]ferrocene and its transition-metal complexes

Abstract

1,1′-Bis[(diphenylphosphino)methyl]ferrocene (dpmf). prepared from 1,1′-bis(chloromethyl)ferrocene and LiPPh2, reacted with [PdCl2(MeCN)2] to give [Pd2Cl2(dpmf )2]1, and treatment of 1 with [Pd3(2,6-Me2C6H3NC)6] in a 1 : 0.66 ratio in the presence of NH4PF6 and 2,6-Me2C6H3NC produced a macrocyclic complex [Pd4(2,6-Me2C6H3NC)8(dpmf )2]4+.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 3191-3192

Preparation of 1,1′-bis[(diphenylphosphino)methyl]ferrocene and its transition-metal complexes

Y. Yamamoto, T. Tanase, I. Mori and Y. Nakamura, J. Chem. Soc., Dalton Trans., 1994, 3191 DOI: 10.1039/DT9940003191

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