Issue 7, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Arenediazonium ion insertion into an iron–phosphine bond; synthesis and crystal structure of [Fe(NO)2{PPh2CH2CH2P(Ph)2NN(C6H4F-p)}][PF6]·OC4H8

Francis L. Atkinson,   Neil G. Connelly,   John G. Crossley  and  A. Guy Orpen  

Abstract

The reaction of [Fe(NO)2(dppe)](dppe = Ph2PCH2CH2PPh2) with [N2C6H4F-p][PF6] gave [Fe(NO)2{PPh2CH2CH2P(Ph)2NN(C6H4F-p)}][PF6] X-ray studies on which revealed the formation of a novel chelating ligand bound to iron through phosphine and η2-N[double bond, length half m-dash]N functionalities and resulting from insertion of an arenediazo group into an iron–phosphorus bond.

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Article information

DOI
https://doi.org/10.1039/DT9940001161
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1161-1162

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Arenediazonium ion insertion into an iron–phosphine bond; synthesis and crystal structure of [Fe(NO)2{PPh2CH2CH2P(Ph)2NN(C6H4F-p)}][PF6]·OC4H8

F. L. Atkinson, N. G. Connelly, J. G. Crossley and A. G. Orpen, J. Chem. Soc., Dalton Trans., 1994, 1161 DOI: 10.1039/DT9940001161

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