Issue 21, 1994

Mechanism of a novel spirocyclisation reaction; intramolecular oxygen transfer to carbon radicals by nitro groups

Abstract

A mechanism for the novel radical spirocyclisation reaction 12 is proposed, and is shown by isotopic labelling to involve transfer of oxygen from an aromatic nitro function to carbon in a cyclohexadienyl radical.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2443-2444

Mechanism of a novel spirocyclisation reaction; intramolecular oxygen transfer to carbon radicals by nitro groups

U. P. Topiwala and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1994, 2443 DOI: 10.1039/C39940002443

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