Novel intramolecular radical spirocyclisation reactions in aromatic nuclei, 22→23 and 30→31, are presented, which mimic a key step in the proposed biosynthesis of the interiorins 1–4 and kadsulignans 5, 6.
S. P. Green and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1994, 2441 DOI: 10.1039/C39940002441
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