Synthesis and crystal structure of [Pd(PPh3)S2B6H8]2: a dimeric metallaheteroborane with heteroatoms acting both as cluster atoms and two-electron donor sites
Abstract
The novel palladadithiaborane dimer [arachno-Pd(PPh3)S2B6H8]2 contains sulfur atoms that are simultaneously cluster atoms and exo-polyhedral two-electron donors to palladium atoms in the adjacent cage.