9-Alkyl 6,7-benzomorphans (1,2,3,4,5,6-hexahydro-11-alkyl-2,6-methano-3-benzazocines) are important selective ligands of sigma receptor sites; their asymmetric synthesis starting with (1R, 2R)- or (1S, 2S)-1-hydroxymethyl-2-alkyl-2-alkyl-1,2-dihydronaphthalene is described.
X. Bai, S. W. Mascarella, W. D. Bowen and F. I. Carroll, J. Chem. Soc., Chem. Commun., 1994, 2401 DOI: 10.1039/C39940002401
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