The reaction of UCl4 with the diphosphinoamido ligand, (Pri2PHC2CH2)2N–, in the presence of oxygen gives rise to the first well characterised uranium(V)–tertiary phosphine complex.
S. J. Coles, P. G. Edwards, M. B. Hursthouse and P. W. Read, J. Chem. Soc., Chem. Commun., 1994, 1967 DOI: 10.1039/C39940001967
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