Issue 14, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Electron transfer rates in a trinuclear mixed-valence iron(III, III, II) molecule: a variable-temperature infrared spectroscopic study

Ruowen Wu,   Samuel K. Arap Koske,   Ross P. White,   Christopher E. Anson,   Upali A. Jayasooriya  and  Roderick D. Cannon  

Abstract

In IR spectra of the mixed-valence compound [FeIII2FeIIO(OOCCMe3)6(C5D5N)3], the bands assigned to in-plane vibration of the central oxygen atom show exceptional temperature dependence, interpreted as being due to electron transfer within the trinuclear cluster, with a rate constant of ca. 1011 s–1 at 300 K.

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Article information

DOI
https://doi.org/10.1039/C39940001657
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1657-1658

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Electron transfer rates in a trinuclear mixed-valence iron(III, III, II) molecule: a variable-temperature infrared spectroscopic study

R. Wu, S. K. A. Koske, R. P. White, C. E. Anson, U. A. Jayasooriya and R. D. Cannon, J. Chem. Soc., Chem. Commun., 1994, 1657 DOI: 10.1039/C39940001657

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