Issue 14, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

New actinide hydrogen transition metal compounds. Synthesis of [K(C12H24O6)][(η-C5Me5)2(Cl)UH6Re(PPh3)2] and the crystal structure of its benzene solvate

Sophie M. Cendrowski-Guillaume,   Monique Lance,   Martine Nierlich,   Julien Vigner  and  Michel Ephritikhine  

Abstract

The title compound is isolated from the reaction of [{U(C5Me5)2(µ-Cl)}3] with [K(18-crown-6)][ReH6(PPh3)2](18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane) and is oxidized by TIBPh4 into the neutral derivative [(C5Me5)2(Cl)UH6Re(PPh3)2]; the 1H NMR spectra reveal that in both complexes, the uranium and rhenium atoms are linked by three bridging hydrides.

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Article information

DOI
https://doi.org/10.1039/C39940001655
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1655-1656

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New actinide hydrogen transition metal compounds. Synthesis of [K(C12H24O6)][(η-C5Me5)2(Cl)UH6Re(PPh3)2] and the crystal structure of its benzene solvate

S. M. Cendrowski-Guillaume, M. Lance, M. Nierlich, J. Vigner and M. Ephritikhine, J. Chem. Soc., Chem. Commun., 1994, 1655 DOI: 10.1039/C39940001655

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