The reaction of PPN[Bi2Co4(CO)10(µ-CO)] with Mo(CO)3(toluene) in THF yields, after slow oxidation, the large clusters, (PPN)2[Bi4Co9(CO)8(µ-CO)8] and (PPN)2[Bi8Co14(CO)12(µ-CO)8][PPN = bis(triphenylphosphine)iminium] which exhibit close-packed arrays of main group elements and transition metal atoms.
K. H. Whitmire and J. R. Eveland, J. Chem. Soc., Chem. Commun., 1994, 1335 DOI: 10.1039/C39940001335
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