The reaction of cyclohexene, C6H10, with Ru3(CO)12 yields the new octaruthenium–benzene cluster [Ru8H4(CO)18(η6-C6H6)] which has been fully characterised in solution by conventional spectroscopic methods and in the solid state by a single crystal X-ray diffraction analysis.
B. F. G. Johnson, C. M. Martin, D. Braga, F. Grepioni and E. Parisini, J. Chem. Soc., Chem. Commun., 1994, 1253 DOI: 10.1039/C39940001253
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