The homoleptic eight coordinate thorium dialkyphosphide, Th[P(CH2CH2PMe2)2]41 reacts with carbon monoxide to give the first reported double insertion product where CO is incorporated into a coordinated secondary alcohol derivative by the coupling of two dialkyl phosphide groups at the same carbon atom.
P. G. Edwards, M. B. Hursthouse, K. M. A. Malik and J. S. Parry, J. Chem. Soc., Chem. Commun., 1994, 1249 DOI: 10.1039/C39940001249
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