Simple allylic amines are easily converted into 4-substituted 1-aza-1,3-dienes 4via organozirconium complexes; the hydrolysis of the azadienes leads to β-substituted α,β-unsaturated aldehydes 5.
J. Barluenga, R. Sanz, R. González and F. J. Fañanás, J. Chem. Soc., Chem. Commun., 1994, 989 DOI: 10.1039/C39940000989
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