Issue 3, 1994

Evidence for concerted extrusion of TeR2 from permethylscandocene tellurolates

Abstract

Use of stereochemical probes shows that both the formation of permethylscandocene tellurolates (via tellurium insertion into Sc–C bonds) and the decomposition of permethylscandocene tellurolates (via extrusion of TeR2) proceed with retention of configuration in the probe, implying concerted transition states for both reactions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 309-310

Evidence for concerted extrusion of TeR2 from permethylscandocene tellurolates

W. E. Piers, J. Chem. Soc., Chem. Commun., 1994, 309 DOI: 10.1039/C39940000309

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