SCHEDULED MAINTENANCE
Unsupported and silica-supported H3PMo12O40 catalysts show a wide temperature range for decomposition on thermal treatment allowing the formation of monoclinic β-MoO3(characterized by Raman spectroscopy and X-ray powder diffraction); this new supported phase leads specifically to dimethoxymethane in the methanol oxidation reaction.
M. Fournier, A. Aouissi and C. Rocchiccioli-Deltcheff, J. Chem. Soc., Chem. Commun., 1994, 307 DOI: 10.1039/C39940000307
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