The switch in local Jahn–Teller distortions of the MnIIIO6 octahedra caused by the topotactic ion-exchange reaction of MnAsO4·H2O to give LiMnAsO4(OH) results in a novel switch from antiferromagnetic to ferromagnetic order within infinite Mn–O–Mn chains in the framework, although in both materials the overall order is antiferromagnetic.
M. A. G. Aranda, J. P. Attfield, S. Bruque and R. B. Von Dreele, J. Chem. Soc., Chem. Commun., 1994, 155 DOI: 10.1039/C39940000155
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