Enantiopure chromenoquinoline epoxides of established configuration are obtained by cyclization of their resolved bromomethoxy(trifluoromethyl)phenylacetates and provide a new route to geibalansine, O-acetylgeibalansine, ribalinine, araliopsine, edulinine and related quinoline alkaloids.
S. A. Barr and D. R. Boyd, J. Chem. Soc., Chem. Commun., 1994, 153 DOI: 10.1039/C39940000153
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