The reaction of GeBr4 with 2 equivalents of Li2[C10H7N](C10H7N = 1-naphthylamido dianion) in tetrahydrofuran (thf)–diethyl ether produces (LiBr·thf)∞ as a product, which has an infinite ‘corrugated’ ladder structure in the solid state and can be regarded as arising from the association of cubes of (LiBr·thf)4.
A. J. Edwards, M. A. Paver, P. R. Raithby, C. A. Russell and D. S. Wright, J. Chem. Soc., Dalton Trans., 1993, 3265 DOI: 10.1039/DT9930003265
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