α-Trimethylsilyl and α-triethylsilyl aldehydes 6 were obtained from trimethylsilyl and triethylsilyl β-bromo enol ethers 1, using a bromine–lithium exchange and a 1–3 migration of the trialkylsilyl group.
L. Duhamel, J. Gralak and A. Bouyanzer, J. Chem. Soc., Chem. Commun., 1993, 1763 DOI: 10.1039/C39930001763
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