Oxidation of 1,8-bis(allylthio)naphthalene with m-chloroperbenzoic acid (m CPBA) gave the monooxide which undergoes three consecutive sigmatropic rearrangements to afford 2-allylnaphtho[1,8-cd]-1,2-dithiole; the mechanism has been studied using deuterium tracer experiments.
N. Furukawa, H. Shima and T. Kimura, J. Chem. Soc., Chem. Commun., 1993, 1762 DOI: 10.1039/C39930001762
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