Addition of 2 equiv. of [WCl2(Ph2PMe)4] to 1,3- or 1,4-phenylenediisocyanate results in rapid oxidative addition of isocyanate affording the bis(imido)phenylene bridged tungsten(IV) complexes 1,3- and 1,4-[{cis,trans-WCl2(Ph2PMe)2(CO)}2(µ-NC6H4N)], respectively; both have been characterised by X-ray crystallography.
G. Hogarth, R. L. Mallors and T. Norman, J. Chem. Soc., Chem. Commun., 1993, 1721 DOI: 10.1039/C39930001721
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