A benzo-dipteridine (BDP) having a bipyridin-6-ylmethyl moiety oxidizes α-hydroxy acids to give α-keto acids in the presence of Zn2+ and Et3N in ButOH, whereas a BDP bearing a bipyridin-5-ylmethyl moiety is unable to oxidize them under the same conditions; this is the first example of a D-lactate dehydrogenase model.
Y. Yano, K. Mitsui, Y. Ohsawa, T. Kobayashi and T. Nabeshima, J. Chem. Soc., Chem. Commun., 1993, 1719 DOI: 10.1039/C39930001719
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