A new molybdenum porphyrin dioxygen complex [MoVIO(tmp)(O2)], formed by the reversible reaction of [MoIVO(tmp) with dioxygen in aprotic solvents at room temperature, is isolated and characterized by temperature-programme desorption mass, IR, 1H NMR, and UV–VIS spectroscopy.
J. Tachibana, T. Imamura and Y. Sasaki, J. Chem. Soc., Chem. Commun., 1993, 1436 DOI: 10.1039/C39930001436
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