Issue 11, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Isolation of a single-insertion intermediate in the catalytic polymerization of propene by a cationic tris(hydrocarbyl) zirconium complex

Claudio Pellecchia,   Alfonso Grassi  and  Adolfo Zambelli  

Abstract

Propene reacts smoothly with the alkene polymerization catalyst [Zr(CH2Ph)3{(η6-PhCH2)B(C6F5)3}]1 to give initially the single-insertion adduct [Zr(ηnCH2Ph)2(CH2CHMeCH2Ph)]+[B(CH2Ph)(C6F5)3]–2, which has been isolated and characterized.

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Article information

DOI
https://doi.org/10.1039/C39930000947
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 947-949

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Isolation of a single-insertion intermediate in the catalytic polymerization of propene by a cationic tris(hydrocarbyl) zirconium complex

C. Pellecchia, A. Grassi and A. Zambelli, J. Chem. Soc., Chem. Commun., 1993, 947 DOI: 10.1039/C39930000947

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