Trapping of a propyl isocyanate intermediate and entropies of activation data are consistent with an elimination–addition mechanism AxhDH+ DN(E1cB) for the hydrolysis of 1-alkyl-1-[(4-chlorophenyl)sulfonyl]-3-n-propylurea, the N1-alkyl derivatives of chlorpropamide, inhibitors of aldehyde dehydrogenase.
M. Bergon, A. Vigroux and P. Tisnès, J. Chem. Soc., Chem. Commun., 1993, 946 DOI: 10.1039/C39930000946
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