N,N-Dimethylaniline and N-methylindole react as nucleophiles through carbon with perfluorobicyclobutylidene 1, to give the unusual products 5a and 5b; Proton Sponge reacts in an analgous way with the systems 2 and 3 but, in this case, give the novel annelated products 8 and 7.
R. D. Chambers, S. R. Korn and G. Sandford, J. Chem. Soc., Chem. Commun., 1993, 856 DOI: 10.1039/C39930000856
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