Proton Sponge (PS) hydrofluoride has been prepared and is totally soluble in acetonitrile; this system was used to generate carbanions from hexafluoropropene and to form carbon–fluorine bonds by reaction with 2,4,6-trichloropyrimidine and by reaction with benzoyl chloride (Proton Sponge hydrochloride is insoluble in acetonitrile).
R. D. Chambers, T. F. Holmes, S. R. Korn and G. Sandford, J. Chem. Soc., Chem. Commun., 1993, 855 DOI: 10.1039/C39930000855
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