Homochiral exo- and endo-[4-2H]-4-protoadamantyl substrates have been found to rearrange with the formation of enantiomerically pure [1-2H]-2-adamantanol; the data indicate that bridged and open 2-adamantyl cations interconvert slowly, in contrast to analogous 4-protoadamantyl cations.
E. Herpers and W. Kirmse, J. Chem. Soc., Chem. Commun., 1993, 160 DOI: 10.1039/C39930000160
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