Novel Stereocontrolled enantiospecific syntheses of (–)-kainic acid and (+)-allokainic acid have been achieved starting from L-serine via two modes of C-2 and C-3 side chain-directed intramolecular protodesilylations of 4-(trimethylsilylmethyl)ethylidenepyrrolidines.
S. Hatakeyama, K. Sugawara and S. Takano, J. Chem. Soc., Chem. Commun., 1993, 125 DOI: 10.1039/C39930000125
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