Three novel, mixed-ligand complexes of ruthenium and osmium are prepared1; the key example [Ru(bpy)2bpaH](PF6)2[bpy = 2,2′-bipyridine; bpaH = bis(picolyl)amine]1 bears a ‘dangling’ pyridine ligand according to X-ray crystallography and has a luminescence lifetime comparable with that of [Ru(bpy)3]2+.
S. K. Sahni, M. G. B. Drew, T. W. Bell and B. S. Brunschwig, J. Chem. Soc., Chem. Commun., 1993, 123 DOI: 10.1039/C39930000123
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