The generation of a C-16 carbocation in the aphidicolane series by the hydrolysis of a 15β,16β- or a 16β,17-epoxide is shown to lead, inter alia, to skeletal rearrangement products arising from the migration of the C(12)–C(13) bond to C-16.
J. R. Hanson, P. B. Hitchcock, A. G. Jarvis and A. H. Ratcliffe, J. Chem. Soc., Perkin Trans. 1, 1992, 1773 DOI: 10.1039/P19920001773
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