Issue 22, 1992

Synthesis, X-ray crystal structure and NMR characterization of a tetrahedral methylmercury complex with the tripod ligand N(CH2CH2PPh2)3

Abstract

The complex [Hg(np3)Me]CF3SO3, which is the first example of a methylmercury complex in an almost regular tetrahedral coordination, is obtained by the reaction of np3[N(CH2CH2PPh2)3] with (HgMe)CF3SO3; the complex has been studied by X-ray analysis in the solid state and NMR spectroscopy in solution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1691-1693

Synthesis, X-ray crystal structure and NMR characterization of a tetrahedral methylmercury complex with the tripod ligand N(CH2CH2PPh2)3

C. A. Ghilardi, P. Innocenti, S. Midollini, A. Orlandini and A. Vacca, J. Chem. Soc., Chem. Commun., 1992, 1691 DOI: 10.1039/C39920001691

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