The crystal structure of [Mn(salpn)(acetate)]2(H2O)3; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]

Nadeem Aurangzeb; Charlotte E. Hulme; Charles A. McAuliffe; Robin G. Pritchard; Michael Watkinson; Ana Garcia-Diebe; Manuel R. Bermejo; Antonia Sousa

doi:10.1039/C39920001524

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The crystal structure of [Mn(salpn)(acetate)]₂(H₂O)₃; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]

Nadeem Aurangzeb, Charlotte E. Hulme, Charles A. McAuliffe, Robin G. Pritchard, Michael Watkinson, Ana Garcia-Diebe, Manuel R. Bermejo and Antonia Sousa

Abstract

The crystal structure of [Mn(salpn)(OAc)]₂(H₂O)₃ shows it to be a polymeric array, with the Mn(salpn) units bridged by acetate groups in an anti–anti configuration, with three hydrogen-bonded water molecules per monomer; the two ligands per monomer are rotated 180° with respect to each other.

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DOI: https://doi.org/10.1039/C39920001524
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1992, 1524-1526

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The crystal structure of [Mn(salpn)(acetate)]₂(H₂O)₃; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]

N. Aurangzeb, C. E. Hulme, C. A. McAuliffe, R. G. Pritchard, M. Watkinson, A. Garcia-Diebe, M. R. Bermejo and A. Sousa, J. Chem. Soc., Chem. Commun., 1992, 1524 DOI: 10.1039/C39920001524

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Journal of the Chemical Society, Chemical Communications

The crystal structure of [Mn(salpn)(acetate)]₂(H₂O)₃; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]

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The crystal structure of [Mn(salpn)(acetate)]₂(H₂O)₃; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]

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