Preparation of the first fluorinated alkenyl isocyanide F2CCF–NC by flash vacuum pyrolysis of [Cr(CO)5(CN–CFCF2)]. Crystal and molecular structure of [Cr(CO)5(CN–CFCF2)] at 125 K

Dieter Lentz; Dagmar Preugschat

doi:10.1039/C39920001523

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Preparation of the first fluorinated alkenyl isocyanide F₂CCF–NC by flash vacuum pyrolysis of [Cr(CO)₅(CN–CFCF₂)]. Crystal and molecular structure of [Cr(CO)₅(CN–CFCF₂)] at 125 K

Dieter Lentz and Dagmar Preugschat

Abstract

Trifluorovinyl isocyanide, F₂C [double bond, length half m-dash] CF–NC, is obtained by flash vacuum pyrolysis of [Cr(CO)₅(CN–CFCF₂)] at 240°C and identified by spectroscopic methods; the structure of the chromium complex [Cr(CO)₅(CN–CFCF₂)] has been elucidated by X-ray crystallography.

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DOI: https://doi.org/10.1039/C39920001523
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1992, 1523-1524

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Preparation of the first fluorinated alkenyl isocyanide F₂CCF–NC by flash vacuum pyrolysis of [Cr(CO)₅(CN–CFCF₂)]. Crystal and molecular structure of [Cr(CO)₅(CN–CFCF₂)] at 125 K

D. Lentz and D. Preugschat, J. Chem. Soc., Chem. Commun., 1992, 1523 DOI: 10.1039/C39920001523

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Journal of the Chemical Society, Chemical Communications

Preparation of the first fluorinated alkenyl isocyanide F₂CCF–NC by flash vacuum pyrolysis of [Cr(CO)₅(CN–CFCF₂)]. Crystal and molecular structure of [Cr(CO)₅(CN–CFCF₂)] at 125 K

Abstract

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Preparation of the first fluorinated alkenyl isocyanide F₂CCF–NC by flash vacuum pyrolysis of [Cr(CO)₅(CN–CFCF₂)]. Crystal and molecular structure of [Cr(CO)₅(CN–CFCF₂)] at 125 K

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