The insertion of norbornene into the Pd–C bond of the cationic phenylpalladium(II) complex [PdPh(pmdien)]OTf (2, pmdien =N,N,N′,N′,N″-pentamethyldiethylenetriamine, OTf = trifluoromethanesulfonate) yields a 1 : 1 enantiomeric mixture of an ortho 2-exo-norbornyl-substituted phenylpalladium(II) compound via selective, intramolecular C–H activation of the phenyl ring.
B. A. Markies, P. Wijkens, H. Kooijman, A. L. Spek, J. Boersma and G. van Koten, J. Chem. Soc., Chem. Commun., 1992, 1420 DOI: 10.1039/C39920001420
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