The novel anion [Rh23N4(CO)20(µ-CO)18]3–, obtained by controlled pyrolysis of [Rh6N(CO)15]–, contains a large metallic polyhedron of idealized C2 symmetry, which has 21 surface metals and encloses a couple of bonded rhodium atoms and four interstitial nitrogen atoms, each connected to five rhodium atoms.
S. Martinengo, G. Ciani and A. Sironi, J. Chem. Soc., Chem. Commun., 1992, 1405 DOI: 10.1039/C39920001405
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