Issue 19, 1992

Mild generation of alkylidenecarbenes from α-mesyloxynitriles of sugars. Application to the synthesis of branched-chain sugars

Abstract

Treatment of O-mesylcyanohydrins of furanos-3-ulose with sodium azide affords vinylazidoderivaties; the intermediary of an alkylidenecarbene is proposed, and reactions to trap such an intermediate are described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1403-1404

Mild generation of alkylidenecarbenes from α-mesyloxynitriles of sugars. Application to the synthesis of branched-chain sugars

M. Pérez-Pérez and M. J. Camarasa, J. Chem. Soc., Chem. Commun., 1992, 1403 DOI: 10.1039/C39920001403

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