An enantioselective and geometrically selective synthesis of the C(1)–C(14) tetraene nitrile unit of calyculin A, using aldol chemistry with (+)-(E)-diisopinocampheylborane and Stille coupling, is described.
A. G. M. Barrett, J. J. Edmunds, J. A. Hendrix, K. Horita and C. J. Parkinson, J. Chem. Soc., Chem. Commun., 1992, 1238 DOI: 10.1039/C39920001238
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