The reductive regioselective bond-cleavage reaction of γ-halo carbonyl compounds with samarium(II) iodide is developed and its utilisation in the enantiospecific synthesis of (–)-oudemansin A is described.
T. Honda, K. Naito, S. Yamane and Y. Suzuki, J. Chem. Soc., Chem. Commun., 1992, 1218 DOI: 10.1039/C39920001218
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