1,6-Diphosphabicyclo[4.4.0]decane, prepared by way of the cyclisation of 1,4-diphosphinobutane to give 1,2-diphosphacyclohexane, prefers a cis-structure to accommodate the long P–P bond; some reactions of this and related bicyclic diphosphines are reported including the conversion into water-sensitive dimethylated dications.
R. W. Alder, C. Ganter, C. J. Harris and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1992, 1170 DOI: 10.1039/C39920001170
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