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Issue 17, 1992
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The synthesis and crystal structure of a remarkable binuclear, double Pd–Cl–H–O–Pd bridged palladium alcohol complex. Catalytic oxidations with molecular oxygen mediated by [{[Me2C(OH)CH2CONMe2]Pd(Cl)NO2}2]

Abstract

The Pd(Cl)NO2 complex of N,N-3-trimethyl-3-hydroxybutyramide is dimeric in the solid state with two Pd–Cl–H–O–Pd hydrogen-bond bridges; however, in solution the complex is monomeric and catalytically active in the oxidation of alkenes.

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Article information


J. Chem. Soc., Chem. Commun., 1992, 1169-1170
Article type
Paper

The synthesis and crystal structure of a remarkable binuclear, double Pd–Cl–H–O–Pd bridged palladium alcohol complex. Catalytic oxidations with molecular oxygen mediated by [{[Me2C(OH)CH2CONMe2]Pd(Cl)NO2}2]

N. H. Kiers, B. L. Feringa, H. Kooijman, A. L. Spek and P. W. N. M. van Leeuwen, J. Chem. Soc., Chem. Commun., 1992, 1169
DOI: 10.1039/C39920001169

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