Issue 14, 1992

Diastereoselective addition of metal-coordinated and ‘naked’ tri-sec-butylborohydrides to a norephedrine-derived 2-acetyloxazolidine

Abstract

The addition of tri-sec-butylborohydrides to the 2-acetyl-1,3-oxazolidine 1 can be directed with high selectivity to either the Si or the Reπ-carbonyl face under chelating or non-coordinating conditions, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1027-1029

Diastereoselective addition of metal-coordinated and ‘naked’ tri-sec-butylborohydrides to a norephedrine-derived 2-acetyloxazolidine

L. Manzoni, T. Pilati, G. Poli and C. Scolastico, J. Chem. Soc., Chem. Commun., 1992, 1027 DOI: 10.1039/C39920001027

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