Hexamethyldistannane 1a reacts with 1,3-dienes 2 highly regio- and stereo-selectively in the presence of a catalytic amount of bis(dibenzylideneacetone)palladium to afford dimerization–double-stannation adducts 3 in high yields.
Y. Tsuji and T. Kakehi, J. Chem. Soc., Chem. Commun., 1992, 1000 DOI: 10.1039/C39920001000
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